Skip to content
Chemistry · Grade 12

Active learning ideas

Polymers and Polymerization

Dive into the world of macromolecules by exploring how tiny building blocks link up to create the plastics, fabrics, and even biological molecules that define our world.

Ontario Curriculum ExpectationsOntario Curriculum: SCH4U, Strand B - Organic Chemistry, B1: Analyse the origins and the properties of a variety of organic compounds that are used in diverse applications.
20–50 minPairs → Whole Class3 activities

Activity 01

Socio-Scientific Issues20 min · Whole Class

Nylon Rope Trick Demonstration

In a fume hood, carefully pour a solution of adipoyl chloride in cyclohexane on top of an aqueous solution of hexamethylenediamine. Students can use forceps to gently pull the polymer film that forms at the interface, creating a continuous strand of nylon.

Compare the processes of addition polymerization and condensation polymerization.

Facilitation TipEnsure all safety precautions are strictly followed, as the chemicals are corrosive and have strong odours.

What to look forUse an exit ticket where students must draw the repeating unit of a polymer given its monomer, or vice versa, for a simple addition polymer like polypropylene.

AnalyzeEvaluateCreateSocial AwarenessDecision-MakingRelationship Skills
Generate Complete Lesson

Activity 02

Socio-Scientific Issues45 min · Small Groups

Polymer Properties Investigation

Provide students with numbered samples of different polymers (e.g., LDPE, HDPE, PET, PVC). They will perform a series of tests for density (sink/float), flexibility, and heat resistance to identify the materials and relate their properties to their known structures.

Explain how the properties of a polymer are related to the structure of its monomer and the bonds between chains.

Facilitation TipEncourage students to create a data table to systematically record their observations before drawing conclusions.

What to look forA research project and presentation where students analyse a specific polymer. They must cover its synthesis, properties, applications, and a full lifecycle analysis of its environmental impact.

AnalyzeEvaluateCreateSocial AwarenessDecision-MakingRelationship Skills
Generate Complete Lesson

Activity 03

Bioplastic Synthesis Lab

Students follow a procedure to create a simple bioplastic from corn starch, water, vinegar, and glycerol. They can then pour the mixture into a mould and let it dry, observing the properties of the resulting material over a few days.

Evaluate the societal and environmental impact of the production and disposal of synthetic polymers.

Facilitation TipHave students vary the amount of glycerol to investigate how a plasticizer affects the flexibility of the final product.

What to look forA unit test question that requires students to compare and contrast addition and condensation polymerization, including balanced chemical equations for a specific example of each.

AnalyzeEvaluateCreateSocial AwarenessDecision-MakingRelationship Skills
Generate Complete Lesson

Templates

Templates that pair with these Chemistry activities

Drop them into your lesson, edit them, and print or share.

A few notes on teaching this unit

Begin by connecting to students' prior knowledge of organic molecules. Use physical models or digital simulations to help visualize the process of chain growth in both addition and condensation reactions. Emphasize the direct link between the molecular structure they draw on paper and the tangible properties of the plastics they handle every day.

Students will be able to explain how different polymerization processes create unique materials and analyse the profound impact these materials have on society and the environment.


Watch Out for These Misconceptions

  • All plastics are the same and have the same properties.

    Plastics are a diverse group of polymers. Their properties, such as strength, flexibility, and melting point, vary significantly based on the monomer used, chain length, branching, and the presence of additives.

  • Polymers are always man-made, artificial materials.

    Many essential biological molecules are natural polymers. Examples include DNA and RNA (polynucleotides), proteins (polypeptides), and starch and cellulose (polysaccharides).

  • If a plastic has a recycling symbol on it, it is always recycled.

    The number inside the chasing arrows symbol is a resin identification code, not a guarantee of recyclability. The ability to recycle a plastic depends on the local municipal facilities' capacity to collect, sort, and process that specific type of material.


Methods used in this brief