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Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium · Semester 1

Rate Equations, Order of Reaction and the Arrhenius Equation

Students will explore how particles need to collide with sufficient energy for a reaction to occur, linking this to reaction speed.

Key Questions

  1. Determine the order of reaction with respect to each reactant from concentration–time graphs or initial-rate experiments, and calculate the rate constant including its units for a given rate equation.
  2. Distinguish between the rate-determining step and subsequent fast steps in a proposed reaction mechanism, assessing whether the mechanism is consistent with the experimentally determined rate equation.
  3. Analyse a Maxwell–Boltzmann energy distribution to explain why a 10 °C rise approximately doubles the rate for many reactions near room temperature, quantifying the argument using the Arrhenius equation.

MOE Syllabus Outcomes

MOE: Particle Theory - MSMOE: Reaction Rates - MS
Level: JC 2
Subject: Chemistry
Unit: Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium
Period: Semester 1

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