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Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium · Semester 1

Acid–Base Equilibria: Ka, pH Calculations and Buffer Solutions

Students will define acids and bases, understand the pH scale, and perform simple pH measurements.

Key Questions

  1. Calculate the pH of a weak acid solution from its Ka and initial concentration, justifying the validity of the approximation [HA] ≈ [HA]₀ and identifying when it breaks down.
  2. Derive the Henderson–Hasselbalch equation from the Ka expression and use it to calculate the pH of a buffer solution, then evaluate how buffer capacity changes as the acid-to-salt ratio deviates from 1:1.
  3. Analyse the titration curve for a weak acid–strong base system, identifying the equivalence point, half-equivalence point, and buffer region, and justify the appropriate choice of indicator using pKa data.

MOE Syllabus Outcomes

MOE: Acids and Bases - MSMOE: pH Scale - MS
Level: JC 2
Subject: Chemistry
Unit: Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium
Period: Semester 1

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