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Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium · Semester 1

Chemical Equilibrium: Kc, Kp and Quantitative Applications

Students will be introduced to the concept of reversible reactions and understand that equilibrium is a dynamic state where forward and reverse reactions occur at equal rates.

Key Questions

  1. Write Kc and Kp expressions for a heterogeneous equilibrium and calculate their numerical values from equilibrium data, converting between Kc and Kp using Kp = Kc(RT)^Δn.
  2. Predict and quantitatively justify the effect of a temperature change on the value of K for an exothermic reaction, distinguishing this thermodynamic effect from the kinetic effect on reaction rate.
  3. Evaluate the industrial conditions chosen for the Haber process by applying both Kp calculations and the Arrhenius equation, resolving the conflict between equilibrium yield and rate of attainment.

MOE Syllabus Outcomes

MOE: Reversible Reactions - MSMOE: Dynamic Equilibrium - MS
Level: JC 2
Subject: Chemistry
Unit: Reaction Kinetics: Rate Equations, Rate Constants and Equilibrium
Period: Semester 1

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