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Energetics: Born-Haber Cycles, Entropy and Gibbs Free Energy · Semester 1

Hess's Law, Calorimetry and Enthalpy Cycles

Students will conduct simple experiments to measure temperature changes during chemical reactions and interpret the results.

Key Questions

  1. Apply Hess's Law to calculate the standard enthalpy change of a reaction that cannot be measured directly, justifying the validity of the indirect thermochemical route.
  2. Analyse the systematic and random errors in a calorimetry experiment and evaluate their quantitative effect on the calculated enthalpy of neutralisation, including a heat-loss correction.
  3. Compare standard enthalpies of combustion across a homologous series of alcohols, explaining the trend using bond enthalpy data and identifying deviations from linearity.

MOE Syllabus Outcomes

MOE: Experimental Chemistry - MSMOE: Data Collection - MS
Level: JC 2
Subject: Chemistry
Unit: Energetics: Born-Haber Cycles, Entropy and Gibbs Free Energy
Period: Semester 1

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